He was discharged after 4 d of hospital stay. Ammonium dichromate is an inorganic compound with the formula (NH 4) 2 Cr 2 O 7.In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium.It is a salt consisting of ammonium ions and dichromate ions.. Ammonium dichromate(VI), (NH 4) 2 Cr 2 O 7 (s), (VERY TOXIC, EXPLOSIVE, DANGEROUS FOR THE ENVIRONMENT) - see CLEAPSS Hazcard HC007. The target organs that. Acute toxicity, Oral (Category 3) Acute toxicity, Inhalation (Category 2) Acute toxicity, Dermal (Category 4) Skin corrosion (Category 1B) Acute aquatic toxicity (Category 1), H400 . Hemodialysis was promptly undertaken . H312 Harmful in contact with skin. Chromium (VI) is more toxic than other oxidation states of the chromium atom because of its greater ability to enter cells and higher . NFPA Code H-2 F-1 R-1 OX SECTION 6 ACCIDENTAL RELEASE MEASURES Ventilate area. 5J18BP595G. H330 Fatal if inhaled. For disposal: the product of the reaction, the green chromium(III) oxide, Cr 2 O 3 (s), is LOW HAZARD but there may be traces of . Acute toxicity, Oral (Category 3) Acute toxicity, Inhalation (Category 2) Acute toxicity, Dermal (Category 4) Skin corrosion (Category 1B) . Poisoning by ammonium dichromate may cause vomiting, pain in the stomach, and metallic taste. Label Elements. H301 Toxic if swallowed. "Acute ammonium dichromate poisoning." Annals of Emergency Medicine 24(4): 748-50. Ammonium dichromate. Absorption of chrome VI compounds through the skin can cause systemic poisoning effecting the kidneys and liver. H317 May cause an allergic skin reaction. South Plainfield, NJ 07080 . Specific target organ toxicity - (repeated exposure) Category 1. Though the history was suggestive of ingestion of ammonium dichromate, I wonder why the authors did not estimate the blood level of chromium in their studied patient. H312 - Harmful in contact with skin. Monoisotopic mass 251.914169 Da. 2 - H272 Carc. Ammonium dichromate | Cr2H8N2O7 | CID 24600 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities . Hazard Statements. Authors Menon Narayanankutty Sunilkumar 1 , Thekkuttuparambil Ananthanarayanan Ajith 2 , Vadakut Krishnan Parvathy 1 Affiliations 1 Department of Pediatrics, Amala Institute of Medical Sciences, Thrissur, Kerala, India. 1 author 2. FIRST AID MEASURES General advice Consult a physician. Ammonium Dichromate AR - Hazards statements H272 - May intensify fire; oxidiser. FDA UNII. 2 - H330 Acute Tox. Acute ammonium dichromate poisoning in a 2 year-old child Indian Journal of Critical Care Medicine, 2014, 18, 757-8 Menon Sunilkumar, Thekkuttuparambil Ajith, Vadakut Parvathy. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Serious eye damage/eye irritation Eyes - Rabbit Result: Severe eye irritation Molecular Formula HCrNO. AMMONIUM DICHROMATE 18 07789-09-5 1232-143-1 H8Cr2N207 256.06 g/mol Water 82 7732 -18 -5 H O 18.00 g/mol 4. H340 May cause genetic defects. Classification Codes. H330 - Fatal if inhaled. Kumar H1, Kumar C1, Parmar K2 Author information Affiliations 2 authors 1. Product name: Ammonium Dichromate . H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. On ingestion, initially there is a relative lack of severe . The target organs . It has been used in pyrotechnics. Open cuts, abraded or irritated skin should not be exposed to this material. Ammonium dichromate [Chromium and chromium compounds] Ammonium dichromate [UN1439] [Oxidizer] Chromic acid, diammonium salt. . Ammonium dichromate is used in photo engraving, dye mordant, pigments, pickling, photography, process engraving, lithography, pyrotechnics, glazes for porcelain and china wares. Ammonium dichromate, ACS, 99.5% min, Thermo Scientific . 3 - H301 Specific target organ toxicity - (repeated exposure) Category 1. . CAS Registry Number. formula: Cr2H8N2O7 Hazard classification & labelling Hazard classification and labelling The 'Hazard classification and labelling' section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Hexavalent chromium refers to chemical compounds that contain the element chromium in the +6 oxidation state. Authors Citing This Paper. H350 May cause cancer. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Ammonium Dichromate CAS-No. Mertz, W. (1969). H340 May cause genetic defects. It is readily ignited and burns to leave a sizable green residue. ChemSpider ID 23002. Danger. 1B - H350 Muta. Acute . INTRODUCTION Acute oral intoxication with hexavalent chromium compounds is rare, although frequently fatal because of the strong oxidizing effects. Company: Hummel Croton Inc. 10 Harmich Rd. : 7789-09-5 . Skin manifestations after industrial exposure of chromate salts are well-known, but little is known about systemic toxicity and its treatment. It is more sensitive to light. AMMONIUM DICHROMATE Chemwatch: 1439 Version No: 4.1.1.1 Safety Data Sheet according to WHS and ADG requirements Issue Date: 04/12/2017 Print Date: 14/11/2019 . Ammonium dichromate is a salt consisting of ammonium ions and dichromate ions, a toxic chemical salt used to sensitize organic emulsion. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 - May cause an allergic skin reaction. H350 May cause cancer. . H317 May cause an allergic skin reaction. CASE REPORT A 48-year-old man drank 150 mL of an aqueous solution containing potassium dichromate 22.5 g in a suicidal attempt and was admitted 7 hours after the ingestion. Ammonium dichromate sc-202937 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION . "Chromium occurrence and function in biological systems." . Ammonium dichromate: Class: Small Molecule: Description: Ammonium dichromate is a chemical compound of hexavalent chromium. Entry into the . SIGNS AND SYMPTOMS: Ammonium dichromate is irritating to the skin and mucous membranes. : 7789-09-5 Ox. H330 Fatal if inhaled. Ammonium dichromate 0.1 - 0.5% CAS No. Ammonium Dichromate Poisoning Himanshu Kumar1 & Chandrakanta Kumar1 & Kanak Parmar2 Received: 14 October2019/Accepted: 30April 2020 # Dr. K C Chaudhuri Foundation 2020 To the Editor: A 2-year-old boy presented with history of multiple episodes of vomiting, copious mucoid loose stools and sluggishness after one hour of ingestion of unknown H314 Causes severe skin burns and eye damage. The target organs that are affected by this poison are the respiratory system, kidneys, liver, eyes and skin. Acute aquatic toxicity. Poisoning in children by ammonium dichromate, an odorless and bright orange-red crystal, are rarely reported. Ammonium dichromate is an odorless, bright orange to red, crystalline powder used in pyrotechnics, fireworks, photography, and in dyes used for screen and color printing. The toxicity of ammonium dichromate puts a bit of a potential damper on carbon and gum printing, especially if one want to work in Europe, where availability might soon become a real problem. Chromium may increase its own toxicity by modifying metal regulatory transcription factor 1, causing the inhibition of zinc-induced metallothionein transcription. Acute poisoning will result in death due to multi-organ failure. Calcium-EDTA therapy had no influence on erythrocyte, serum, or urine chromium level, but contributed, however, to a significant increase in chromium elimination rate in the dialysate. Toxicity . ORCIDs linked to this article Parmar K, 0000-0003-2851-5455 Abstract Full text Similar Articles Ammonium Dichromate Poisoning. Poisoning in children by ammonium dichromate, an odorless and bright orange-red crystal, are rarely reported. Circulatory collapse may follow with weak and rapid pulse, shallow respiration, and clammy skin. Thermal decomposition of ammonium dichromate is initiated by local heating to 190 C. 1, 2, 3 We report the accidental ingestion of ammonium dichromate by a child that led to the development of severe gastroenteritis, renal failure, hepatic injury, coagulopathy, coma, shock, and death. Ammonium dichromate is a chemical compound of hexavalent chromium. the whole bit . H301 Toxic if swallowed. 1B - H360FD Acute Tox. Acute Toxicity (Inhalation) Category 2, Reproductive Toxicity Category 1B, Specific target organ toxicity - repeated Ammonium Dichromate can't be shipped by air, its a strong carcinogen etc. Chronic aquatic toxicity (Category 1), H410 : GHS Label elements : : 7789-09-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Signal Word. himanshu kumar and colleagues from the department of pediatrics, king george's medical university, lucknow, india recently reported an interesting case of ammonium dichromate poisoning.the study is published in the indian journal of pediatrics.chromium (cr) is a strong oxidant and poisoning usually begins with gastrointestinal symptoms Early deaths are generally associated with shock. Flame and sparks spread rapidly through the mass, and if confined, it may become explosive. Acute ammonium dichromate poisoning in a 2 year-old child . It has been used in pyrotechnics. If breathing is difficult, give oxygen.Poisonous material After skin contact: Take victim to hospital immediately.Remove contaminated clothing and shoes.Wash off with soap and plenty of water. Category 1. Sol. Poisoning in children by ammonium dichromate ,an odorless and bright orangered crystal, are rarely reported. Synonym: Ammonium Bichromate : CAS-No. System Generated Number. - Charge. Do NOT be tempted to mix other chemicals with the ammonium dichromate (VI). H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Ammonium dichromateRevision Date 19-Jan-2018 Signal Word Danger Hazard Statements May intensify fire; oxidizer May form combustible dust concentrations in air Toxic if swallowed Harmful in contact with skin Fatal if inhaled Causes severe skin burns and eye damage May cause allergy or asthma symptoms or breathing difficulties if inhaled Product name : Ammonium dichromate Product Number : 402826 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . Reproductive toxicity, category 1B H360 Respiratory sensitization, category 1 H334 Skin sensitization, category 1 H317 . Ammonium dichromate is sometimes known as Vesuvian Fire, because of its use in demonstrations of tabletop "volcanoes". H314 Causes severe skin burns and eye damage. doi: 10.4103/0972-5229.144024. Ammonium dichromate Acute toxicity LD50 Oral - Rat - 53 mg/kg LC50 Inhalation - Rat - 4 h - 0.2 mg/l - dust/mist LD50 Dermal - Rabbit - 1,860 mg/kg Skin corrosion/irritation Causes skin burns. Acute poisoning will result in death due to multi-organ failure. Department of Pediatrics, King George's Medical University, Lucknow, India. King George's Medical University, Lucknow, India. Case Report UN1439. It acts as a catalyst and a source of nitrogen in the laboratory and as the photoactive site. 1B - H340 Repr. (1, 7, 2, 3, 4) If ammonium dichromate is heated in a closed container, it may rupture due to the decomposition of the material. Chromium (Cr) is a strong oxidant and poisoning usually begins with gastrointestinal symptoms progressing to multiorgan failure. Chronic aquatic toxicity. Mol. H301 - Toxic if swallowed. Lethal dose of chromium salt varies between 6 to 8 g in adults [ 1 , 2] and 1 g in children. 7789-09-5. H314 - Causes severe skin burns and eye damage. Acute poisoning will result in death due to multiorgan failure. Registry Numbers. Consult a physician.Flush with water for 15 minutes.Get medical assistance if irritation develops. Average mass 252.065 Da. Author Citing Papers Author's Papers Author's Citations In case of fire: Use a tri-class dry chemical fire extinguisher (P370+P378). Category 1. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. [ 1] in their statement that the diagnosis of a poisoning case mainly depends on the history, direct identification of the compound, if available and clinical examination. Specific target organ toxicity - repeated exposure (Category 1), H372 . H312 Harmful in contact with skin. "Successful treatment of a patient suffering from severe acute potassium dichromate poisoning with liver transplantation." Transplantation 69(11): 2454-5. . 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